Meghan took to the podium, telling the audience how honoured she was to be there, before handing over the microphone to her co-host, former award victor Neil Heritage.
Markle and Chopra first met at a party in Toronto, Canada - where Meghan, 36, filmed Suits - two years ago.
Meghan Markle wore a pantsuit by Alexander McQueen while attending an event on Thursday evening. The event celebrates the achievements of wounded, injured and sick servicemen and women who were part of sporting and adventures over the past years, People reported.
However, when she turned to her co-host to read out the nominations, the poor fella seemed to get a little bit flustered whilst stood next to the future royal.
It soon became clear, however that Heritage was going through a slight panic as he stood beside the Suits star at the lectern.
Meghan Markle responded with grace and humour after an awards ceremony mix-up caused confusion.
Meghan laughed, and the audience laughed with her, as she stepped in to help.More news: Alexa Can Now Send Texts: Here's How
"Who's done the notes, eh?" he said ruefully before continuing.
Harry took to the stage later on to present the Henry Worsley Award, named for his late friend.
But the former Suits actor took it all in stride like the pro she is, and her partner powered through the awkward moment by laughing. "It could change their life, and that of their families too".
The world is now squarely obsessed with Meghan Markle.
Prior to the awards ceremony, the couple met with the inspiring nominees, participants and supporters.